Controlled Rate Thermal Analysis (CRTA) as New Method to Control the Specific Surface in Hydroxyapatite Thin Coatings

  1. Peón, E. 12
  2. García-Galván, F.R. 1
  3. El Hadad, A. 13
  4. Jiménez-Morales, A. 4
  5. Galvan, J.C. 1
  1. 1 Centro Nacional de Investigaciones Metalúrgicas
    info

    Centro Nacional de Investigaciones Metalúrgicas

    Madrid, España

    ROR https://ror.org/04m7z8d34

  2. 2 Universidad de La Habana
    info

    Universidad de La Habana

    La Habana, Cuba

    ROR https://ror.org/04204gr61

  3. 3 Al Azhar University
    info

    Al Azhar University

    Cairo, Egipto

    ROR https://ror.org/05fnp1145

  4. 4 Universidad Carlos III de Madrid
    info

    Universidad Carlos III de Madrid

    Madrid, España

    ROR https://ror.org/03ths8210

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Libro:
Modern Technologies for Creating the Thin-film Systems and Coatings

Año de publicación: 2017

Tipo: Capítulo de Libro

DOI: 10.5772/66468 GOOGLE SCHOLAR lock_openAcceso abierto editor

Resumen

The control of the texture in synthetic hydroxyapatite ceramics had limited their application in the field of the materials for bone implantation, even more when it is used as a filling in cements and other formulations in orthopedic surgery. The present article shows preliminary results demonstrating the effectiveness of a modification of the controlled rate thermal analysis (CRTA), developed by J. Rouquerol, used for the preparation of ceramic materials with controlled textural characteristics, during the formation of ceramic powders of synthetic hydroxyapatite at low temperatures. The thermal treatments of the hydroxyapatite were carried out in a device connected to a computer, to control temperature and pressure system, keeping the decomposition speed constant. Results, reported when preparing ceramic powders of hydroxyapatite at 300 and 850°C under controlled pressure, using synthetic hydroxyapatite with a Ca/P molar ratio equal to 1.64, were checked using IR spectroscopy and X‐ray diffraction, showed that the formed phase corresponds to that of crystalline hydroxyapatite, even at 300°C of maximum temperature. Values of specific surface (BET) between 17 and 66 m2/g, with pore size in the range of 50–300 Å in both cases are obtained by N2 absorption isotherms, when analyzing the isotherms of nitrogen absorption.

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