Technologies for the 21st centurycarbon nanotubes as adsorbents of metals

  1. Alguacil, Francisco José 1
  2. Cerpa, Arisbel 2
  3. Lado, Isabel 2
  4. López, Félix A. 1
  1. 1 Centro Nacional de Investigaciones Metalúrgicas (CENIM).CSIC
  2. 2 Universidad Europea de Madrid, Dpto. de Electromecánica y Materiales
Revista:
Revista de metalurgia

ISSN: 0034-8570

Año de publicación: 2014

Volumen: 50

Número: 3

Páginas: 25-25

Tipo: Artículo

DOI: 10.3989/REVMETALM.025 DIALNET GOOGLE SCHOLAR lock_openAcceso abierto editor

Otras publicaciones en: Revista de metalurgia

Resumen

Tanto en el pasado como hoy en día, cuando la palabra “nano” aparece en cualquier sitio inmediatamente suscita atención e interés; por eso y desde su descubrimiento hace cerca de veinte años, los nanotubos de carbono interesaron tanto a científicos como a industriales, que utilizaron las propiedades de estos nanomateriales en una serie de aplicaciones. Entre éstas, se incluye la eliminación de metales tóxicos, y otros con un cierto valor económico, de medios acuosos, problemática que además tiene unas implicaciones económicas y sociales importantes. Este trabajo revisa los avances más recientes (años 2009–2013) de la utilización de estos nanotubos de carbono en la eliminación de una serie de metales contenidos en distintos medios acuosos.

Referencias bibliográficas

  • Abdel Salam, M., Mohamed, R.M. (2013). Removal of antimony (III) by multi-walled carbon nanotubes from model solution and environmental samples. Chem. Eng. Res. Des. 91, 1352–1360.
  • AddoNtim, S., Mitra, S. (2012). Adsorption of arsenic on multiwall carbon nanotube-zirconia nanohybrid for potential drinking water purification. J. Colloid. Interf. Sci. 375, 154–159.
  • Ahmadzadeh Tofighy, M., Mohammadi, T. (2011). Adsorption of divalent heavy metal ions from water using carbon nanotube sheets. J. Hazard. Mater. 185, 140–147.
  • Atieh, M.A. (2011). Removal of chromium(VI) from polluted water using carbon nanotubes supported with activated carbon. Procedia Environ. Sci. 4, 281–293.
  • Bahgat, M., Farghali, A.A., El Rouby, W.M.A., Khedr, M.H. (2011). Synthesis and modification of multi-walled carbon nano-tubes (MWCNTs) for water treatment applications. J. Anal. Appl. Pyrolysis 92, 307–313.
  • Bayazit, S.S., Inci, I. (2013). Adsorption of Pb(II) ions from aqueous solutions by carbon nanotubes oxidized different methods. J. Ind. Eng. Chem. 19, 2064–2071.
  • Chen, C.L., Wang, X.K., Nagatsu, M. (2009a). Europium adsorption on multiwall carbon nanotube/iron oxide magnetic composite in the presence of polyacrylic acid. Environ. Sci. Technol. 43, 2362–2367.
  • Chen, C., Hu, J., Shao, D., Li, J., Wang, X. (2009b). Adsorption behaviour of multiwall carbon nanotube/iron oxide magnetic composites for Ni(II) and Sr(II). J. Hazard. Mater. 164, 923–928.
  • Chen, L., Yu, S., Liu, B., Zuo, L. (2012). Removal of radiocobalt from aqueous solution by different sized carbon nanotubes. J. Radioanal. Nucl. Chem. 292, 785–791.
  • Chen, B., Zhu, Z., Ma, J., Qiu, Y., Chen, J. (2013). Surfactant assisted Ce-Fe mixed oxide decorated multiwalled carbon nanotubes and their arsenic adsorption performance. J. Mater. Chem. A 1, 11355–11367.
  • de Agreda, D., García-Díaz, I., López, F.A., Alguacil, F.J. (2011). Supported liquid membranes technologies in metals removal from liquid effluents. Rev. Metal. 47 (2), 146–168.
  • Díaz-Flores, P., López-Urias, F., Terrones, M., Rangel-Méndez, R. (2009). Simultaneous adsoprtion of Cd2+ and phenol on modified N-doped carbon nanotubes: experimental and DFT studies. J. Colloid. Interf. Sci. 334, 124–131.
  • Díaz-Pavon, A., Cerpa, A., Alguacil, F.J. (2014). Processing of indium(III) solutions via ion exchange with Lewatit K-2621 resin. Rev. Metal. 50 (2), e010.
  • Fasfous, I.I., Dawoud, J.N. (2012). Uranium(VI) sorption by multiwalled carbon nanotubes from aqueous solution. Appl. Surf. Sci. 259, 433–440.
  • Gao, Z., Bandosz, T., Zhao, Z., Han, M., Qiu, J. (2009). Investigation of factors affecting adsorption of transition metal son oxidized carbon nanotubes. J. Hazard. Mater. 167, 357–365.
  • Geyikci, F., Coruh, S., Kilic, E. (2013). Development of experimental results by artificial neural network mode for adsorption of Cu2+ using single wall carbon nanotubes. Separ. Sci. Technol. 48, 1490–1499.
  • Gupta, V.K., Agarwal, S., Saleh, T.A. (2011a). Chromium removal by combining the magnetic properties of iron oxide with adsorption properties of carbon nanotubes. Water Res. 45, 2207–2212.
  • Gupta, V.K., Agarwal, S., Saleh, T.A. (2011b). Synthesis and characterization of alumina-coated carbon nanotubes and their application for lead removal. J. Hazard. Mater. 185, 17–23.
  • Hamza, I.A.A., Martincigh, B.S., Ngila, J.C., Nyamori, V.O. (2013). Adsorption studies of aqueous Pb(II) onto sugarcane bagasse/multi-walled carbon nanotube composite. Phys. Chem. Earth 66, 157–166.
  • Hu, J., Chen, C., Zhu, X., Wang, X. (2009). Removal of chromium from aqueous solution by using oxidized multiwalled carbon nanotubes. J. Hazard. Mater. 162, 1542–1550.
  • Hu, Z.-J., Cui, Y., Liu, S., Yuan, Y., Gao, H.-W. (2012). Optimization of ethylenediamine-grafted multi-walled carbon nanotubes for solid-phase extraction of lead cations. Environ. Sci. Pollut. Res. 19, 1237–1244.
  • Jamshidi Shadbad, M., Mohebbi, A., Soltani, A. (2011). Mercury(II) removal from aqueous solutions by adsorption on multi-walled carbon nanotubes. Korean J. Chem. Eng. 28, 1029–1034.
  • Kabbashi, N.A., Atieh, M.A., Al-Mamun, A., Mirghami, M.E.S., Alam, M.D.Z., Yahya, N. (2009). Kinetic adsorption of application of carbon nanotubes for Pb(II) removal from aqueous solution. J. Environ. Sci. 21, 539–544.
  • Kosa, S.A., Al-Zhrani, G., Salam, M.A. (2012). Removal of heavy metals from aqueous solutions by multi-walled carbon nanotubes modified with 8-hydroxyquinoline. Chem. Eng. J. 181–182, 159–168.
  • Kuo, G. (2009). Water purification of removal aqueous copper(II) by as-grown and modified multi-walled carbon nanotubes. Desalination 249, 781–785.
  • Li, Y., Liu, F., Xia, B., Du, Q., Zhang, P., Wang, D., Wang, Z., Xia, Y. (2010). Removal of copper from aqueous solution by carbon nanotube/calcium alginate composites. J. Hazard. Mater. 177, 876–880.
  • Li, J., Chen, S., Sheng, G., Hu, J., Tan, X., Wang, X. (2011). Effect of surfactants on Pb(II) adsorption from aqueous solutions using oxidized multiwall carbon nanotubes. Chem. Eng. J. 166, 551–558.
  • Li, C., Xu, X., Bao, C,-L., Wang, H.-F., Liu, L., Liu, X.-T. (2012). Adsorption of Au(III) and Pd(II) in solution of 2, 2′-diaminodiethylamine modified multiwalled carbon nanotubes. Chem. J. Chinese Universities 33, 586–590.
  • Liu, W., Xu, S., Li, C., Yuan, G. (2012). Alkali-earth metal adsorption behaviors on capped single-walled carbon nanotubes base on first-principle calculation. Diam. Relat. Mater. 29, 59–62.
  • Liu, Y.-X., Yan, J.-M., Yuan, D.-X., Li, Q.-L., Wu, X.-Y. (2013). The study of lead removal from aqueous solution using an electrochemical method with a stainless steel net electrode coated with single wall carbon nanotubes. Chem. Eng. J. 218, 81–88.
  • Lu, S., Xu, J., Zhang, C., Niu, Z. (2011a). Adsorption and desorption of radionuclide europium(III) on multiwalled carbon nanotubes studied by batch techniques. J. Radioanal. Nucl. Chem. 287, 893–898.
  • Lu, S., Chen, L., Dong, Y., Chen, Y. (2011b). Adsorption of Eu(III) on iron oxide/multiwalled carbon nanotube magnetic composites. J. Radioanal. Nucl. Chem. 288, 587–593.
  • Maggini, L., Raquez, J.-M., Marega, R., Jensen Ahrens, J., Pineux, F., Meyer, F., Dubois, P., Bonifazi, D. (2013). Magnetic poly(vinylpyridine)-coated carbon nanotubes: an efficient supramolecular tool for wastewater purification. ChemSusChem. 6 (2), 367–373.
  • Mobasherpour, I., Salahi, E., Ebrahimi, M. (2012). Removal of divalent nickel cations from aqueous solution by multiwalled carbon nano tubes: equilibrium and kinetic processes. Res. Chem. Intermed. 38, 2205–2222.
  • Mokhodoeva, O.B., Malikov, D.A., Molochnikova, N.P., Zakharchenko, F.A., Perevalov, S.A., Myasoedova, G.V., Kulyako, Y.M., Tkachev, A.G., Mischenko, S.V., Myasoedov, B.F. (2011). Carbon nanotubes: potential uses in radionuclide concentration. Russ. J. Gen. Chem. 81, 1972–1979.
  • Mubarak, N.M., Alicia, R.F., Abdullah, E.C., Sahu, J.N., Ayu Haslija, A.B., Tan, J. (2013a). Statistical optimization and kinetic studies on removal of Zn2+ using functionalized carbon nanotubes and magnetic biochar. J. Environ. Chem. Eng. 1, 486–495.
  • Mubarak, N.M., Ruthiraan, M., Sahu, J.N., Abdullah, E.C., Jayakumar, N.S., Sajuni, N.R., Tan, J. (2013b). Adsorption and kinetic study on Sn2+ removal using modified carbon nanotube and magnetic biochar. Int. J. Nanosci. 12 (6). 1.350.044.
  • Murthy Bandaru, N., Reta, N., Dalal, H., Ellis, A.V., Shapter, J., Voelcker, N.H. (2013). Enhanced adsorption of mercury ions on thiol derivatized single wall carbon nanotubes. J. Hazard. Mater. 261, 534–541.
  • Naderi Behdani, F., Talebizadeh Rafsanjani, A., Torab-Mostaedi, M., Koochaki Mohammadpour, S.M.A. (2013). Adsorption ability of oxidized multiwalled carbon nanotubes towards aqueous Ce(III) and Sm(III). Korean J. Chem. Eng. 30, 448–455.
  • Pérez-Aguilar, N.V., Muñoz-Sandoval, E., Díaz-Flores, P.E., Rangel-Méndez, J.R. (2010). Adsorption of cadmium and lead onto oxidized nitrogen-doped multiwall carbon nanotubes in aqueous solution: equilibrium and kinetics. J. Nanopart. Res. 12, 467–480.
  • Pérez-Aguilar, N.P., Díaz-Flores, P.E., Rangel-Méndez, J.R. (2011). The adsorption kinetics of cadmium by three different types of carbon nanotubes. J. Colloid. Interf. Sci. 364, 279–287.
  • Pyrzynska, K. (2010). Sorption of Cd(II) onto carbon-based materials-a comparative study. Microchim. Acta 169, 7–13.
  • Pyrzynska, K., Bystrzejewski, M. (2010). Comparative study of heavy metal ions sorption onto activated carbon, carbon nanotubes, and carbon-encapsulated magnetic nanoparticles. Colloids Surf., A. 362, 102–109.
  • Regel-Rosocka, M., Alguacil, F.J. (2013). Recent trends in metals extraction. Rev. Metal. 49 (4), 292–316.
  • Ren, C., Kang, B., Chang. S.-Q., Li, J., Shen, W.-T., Dai, M.-Z., Dong, Y., Dai, Y,-D. (2013). Chitosan functionalized carbon nanotubes for iron ion containing wastewater treatment. Atom. Energy Sci. Technol. 47, 1101–1106.
  • Rosenzweig, S., Sorial, G.A., Sahle-Demessie, E., Mack. J. (2013). Effect of acid and alcohol network forces within functionalized multiwall carbon nanotubes bundles on adsorption of copper(II) species. Chemosphere 90, 395– 402.
  • Saber Tehrani, M., Azar, P.A., Namin, P.E., Dehaghi, S. (2013). Renoval of lead ions from wastewater using functionalized multiwalled carbon nanotubes with tris (2-aminoethyl) amine. J. Environ. Prot. 4, 529–536.
  • Salam, M.A., Al-Zhrani, G., Kosa, S.A. (2012). Simultaneous removal of copper(II), lead(II), zinc(II) and cadmium(II) from aqueous solutions by multi-walled carbon nanotubes. Comptes Rendus Chimie 15, 398–408.
  • Schier, A., Zanker, H. (2009). Aqueous suspensions of carbon nanotubes: surface oxidation, colloidal stability and uranium sorption. Environ. Pollut. 157, 1088–1094.
  • Shao, D., Chen, C., Wang, X. (2012). Application of polyaniline and multiwalled carbon nanotube magnetic composites for removal of Pb(II). Chem. Eng. J. 185–186, 144–150.
  • Sheng, G., Li, J., Shao, D., Hu, J., Chen, C., Chen, Y., Wang, X. (2010). Adsoprtion of copper(II) on multiwalled carbon nanotubes in the absence and presence of humic or fulvic acids. J. Hazard. Mater. 178, 333–340.
  • Soliman, E.M., Marwani, H.M., Albishri, H.M. (2013). Novel solid-phase extraction based on functionalization of multiwalled carbon nano tubes with 5-aminosalicylic acid for preconcentration of Pb(II) in water samples prior to determination by ICP-OES. Environ. Monit. Assess. 185 (12), 10269–10280.
  • Tian, X., Li, T., Yang, K., Xu, Y., Lu, H., Lin, D. (2012). Effect of humic acids on physicochemical property and Cd(II) sorption of multiwalled carbon nanotubes. Chemosphere 89, 1316–1322.
  • Tong, S., Zhao, S., Zhou, W., Li, R., Jia, Q. (2011). Modification of multi-walled carbon anotubes with tannic acid for the adsorption of La, Tb and Lu ions. Microchim. Acta 174, 257–264.
  • Vadahanambi, S., Lee, S.-H., Kim, W.J., Oh, I.-K. (2013). Arsenic removal from contaminated water using threedimensional graphene-carbon nanotube-iron oxide nanostructure. Environ. Sci. Technol. 47, 10510–10517.
  • Velickovic, Z.S., Bajic, Z.J., Ristic, M.D., Djokic, V.R., Marinkovic, A.D., Uskokovic, P.S., Vuruna, M.M. (2013). Modification of multi-wall carbon nanotubes for the removal of cadmium, lead and arsenic from waste water. DJNB. 8 (2), 501–511.
  • Vellaichamy, S., Palanivelu, K. (2011). Preconcentration and separation of copper, nickel and zinc in aqueous samples by flame absorption spectrometry after column solid-phase extraction onto MWCNTs impregnated with D2EHPATOPO mixture. J. Hazard. Mater. 185, 1131–1139.
  • Venkata Ramana, D.K., Yu, J.S., Seshaiah, K. (2013). Silver nanoparticles deposited multiwalled carbon nanotubes for removal of Cu(II) and Cd(II) from water: surface, kinetic, equilibrium, and thermal adsorption properties. Chem. Eng. J. 223, 806–815.
  • Vukovic, G.D., Marinkovic, A.D., Colic, M., Ristic, M.D., Aleksic, R., Peric-Grujic, A.A., Uskokovic, P.S. (2010). Removal of cadmium from aqueous solutions oxidized and ethylenediamine-functionalized multi-walled carbon nanotubes. Chem. Eng. J. 157, 238–248.
  • Vukovic, G.D., Marinkovic, A.D., Skapin, S.D., Ristic, M.D., Aleksic, R., Peric-Grujic, A.A., Uskokovic, P.S. (2011). Removal of lead from water by amino modified multiwalled carbon nanotubes. Chem. Eng. J. 173, 855–865.
  • Wang, J., Li, Z., Li, S., Qi, W., Liu, P., Liu, F., Ye, Y., Wu, L., Wang, L., Wu, W. (2013). Adsorption of Cu(II) on oxidized multi-walled carbon nanotubes in the presence of hydroxylated and carboxylated fullerenes. PLoS ONE 8 (8), e72475.
  • Xu, Y.-J., Arrigo, R., Liu, X., Su, D.-S. (2011). Characterization and use of functionalized carbon nanotubes for the adsorption of heavy metal anions. New Carbon Mater. 26, 57–62.
  • Yang, S., Li, J., Shao, D., Hu, J., Wang, X. (2009). Adsorption of Ni(II) on oxidized multi-walled carbon nanotubes: effect of contact time, pH, foreign ions and PAA. J. Hazard. Mater. 166, 109–116.
  • Yang, S., Hu, J., Chen, C., Shao, D., Wamng, X. (2011). Mutual effects of Pb(II) and humic acid adsorption on multiwalled carbon nanotubes/polyacrylamide composites from aqueous solutions. Environ. Sci. Technol. 45, 3621–3627.
  • Yang, W., Ding, P., Zhou, L., Yu, J., Chen, X., Jiao, F. (2013). Preparation of diamine modified mesoporous silica on multi-walled carbon nanotubes for the adsorption of heavy metals in aqueous solution. Appl. Surf. Sci. 282, 38–45.
  • Yavari, R., Huang, Y.D., Ahmadi, S.J. (2011). Adsorption of cesium (I) from aqueous solution using oxidized multiwall carbon nanotubes. J. Radioanal. Nucl. Chem. 287, 393–401.
  • Yavari, R., Davarkhah, R. (2013). Application of modified multiwall carbon nanotubes as a sorbent for zirconium (IV) adsorption from aqueous solution. J. Radioanal. Nucl. Chem. 298, 835–845.
  • Yu, F., Wu, Y., Ma, J., Zhang, C. (2013). Adsorption of lead on multi-walled carbon nanotubes with different outer diameter and oxygen contents : kinetics, isotherms and thermodynamics. J. Environ. Sci. 25, 195–203.
  • Zhang, C., Sui, J., Li, J., Tang, Y., Cai, W. (2012). Efficient removal of heavy metal ions by thiol-functionalized superparamagnetic carbon nanotubes. Chem. Eng. J. 210, 45–52.
Fuente de los datos: Dialnet